A reappraisal of the stratigraphy and depositional development of the Upper Greensand (Late Albian) of the Devizes district,southern England     

M.A. Woods  I.P. Wilkinson  G.K. Lott  K.A. Booth  A.R. Farrant  P.M. Hopson  A.J. Newell 《Proceedings of the Geologists' Association. Geologists' Association》2008,119(3-4):229-244

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Sediment Nitrogen Fixation: a Call for Re-evaluating Coastal N Budgets     

Silvia E. Newell  Mark J. McCarthy  Wayne S. Gardner  Robinson W. Fulweiler 《Estuaries and Coasts》2016,39(6):1626-1638

Coastal ocean primary productivity is often limited by nitrogen (N) availability, which is determined by the balance between N sources (e.g., N-fixation, groundwater, river inputs, etc.) and sinks (e.g., denitrification, sediment burial, etc.). Historically, heterotrophic N-fixation in sediments was excluded as a significant source of N in estuarine budgets, based on low, indirectly measured rates (e.g., acetylene reduction assay) and because it was unnecessary to achieve mass balance. Many recent studies using net N₂ flux measurements have shown that sediment N-fixation can equal or exceed N₂ loss. In an effort to quantify N₂ production and consumption simultaneously, we measured N-fixation and denitrification directly in sediment cores from a temperate estuary (Waquoit Bay, MA). N-fixation, dissimilatory nitrate reduction to ammonium, and denitrification occurred simultaneously, and the net N₂ flux shifted from uptake (N-fixation) to efflux (denitrification) over the 120-h incubation. Evidence for N-fixation included net ²⁸N₂ and ³⁰N₂ uptake, ¹⁵NH₄ ⁺ production from ³⁰N₂ additions, ¹⁵N_{organic matter} production, and nifH expression. N-fixation from ³⁰N₂ was up to eight times higher than potential denitrification. However, N-fixation calculated from ¹⁵NO₃ ^? was one half of the measured fixation from ³⁰N₂, indicating that ¹⁵NO₃-isotope labeling calculations may underestimate N-fixation. These results highlight the dynamic nature of sediment N cycling and suggest that quantifying individual processes allows a greater understanding of what net N₂ fluxes signify and how that balance varies over time.  相似文献   

Influence of sea surface temperatures on air temperatures in the tropics   总被引：1，自引：0，他引：1  

Z.-X. Wu  R. E. Newell 《Climate Dynamics》1998,14(4):275-290

Interannual variations of tropical tropospheric temperatures are closely related to sea surface temperature (SST) changes in the tropical eastern Pacific (TEP). This study investigated the physical mechanisms for such an air-sea interrelationship. SSTs and latent heat flux were analyzed to find the unique properties of their variations during El Niño. A Gill-type model was used to investigate how a local heat source communicates with the entire tropics. Radiative fluxes in the tropics were evaluated to search for the factors limiting air temperature increases when warm SSTs remain in the TEP. We found that interannual variabilities of SST and latent heat flux are dominated by the variations in the TEP region. The SST variations there have three unique properties that allow the ocean to influence the atmosphere effectively: large magnitude, long persistence, and spatial coherence. The Gill-type model shows that a local heat source can warm the entire tropical troposphere when the heat source is near the equator. Released latent heat in the heat source region and forced adiabatic subsidence elsewhere in the tropics warm the atmosphere. As a result, a local heat source warms the entire tropical strip. The forced subsidence depresses clouds, allowing more infrared radiation to leave the atmosphere and preventing further atmospheric warming when warm SSTs remain in the TEP. This finding is verified by reanalysis data from the National Centers for Environmental Prediction.  相似文献   

Phenolics and Proteins Affecting Palatability of Spartina Leaves to the Gastropod Littoraria irrorata     

Felix  Bärlocher Steven Y.  Newell 《Marine Ecology》1994,15(1):65-75

Along the southeastern coast of the United States, the saltmarsh periwinkle Littoraria irrorata is a major consumer of Spartina alterniflora . It prefers to feed on dead rather than living plants. During senescence and early decay, S. alterniflora leaves become colonized by fungi, their phenolic content declines, and their lipid content increases. In this study, the food preferences of L. irrorata were assessed by offering intact leaves or leaf powder suspended in agar. Relative palatabilities were determined by measuring the weight loss of intact leaves, or by estimating the area of feeding marks left on the surface of leaf powder suspensions. Both techniques demonstrated a clear preference for standing dead rather than yellow-green (senescent) leaves. Yellow-green leaves contained methanol-soluble feeding deterrents. A comparable deterrent effect could be achieved by adding ferulic acid, a phenolic compound common in yellow-green S. alterniflora , to leaf powder. The deterrent effects of methanol extracts or ferulic acid could be neutralized by simultaneously adding fungal mycelium or BSA. Littoraria irrorata preferred leaves colonized by fungi or bacteria over sterile leaves. When offered a choice of sterile leaves colonized by different fungi, the results were variable. In one experiment, L. irrorata clearly preferred one of three leaffungus combinations. The same preference was shown after the food items were treated with methanol/chloroform to remove lipids. In a second experiment with four other fungal strains, there was only a clear preference for one leaf-fungus combination after removal of lipids. The results suggest that the saltmarsh periwinkle prefers S. alterniflora leaves with low concentrations of phenolic deterrents, most likely ferulic acid, and with sufficient fungal biomass. The food choice may be influenced to a smaller degree by fungal components, which, depending on the species or strain, may be lipids or other compounds.  相似文献   

Rifts,rivers and climate recovery: A new model for the Triassic of England     

Andrew J. Newell 《Proceedings of the Geologists' Association. Geologists' Association》2018,129(3):352-371

Triassic basins of England developed under a regime of largely W–E extension and progressed from non-marine fluvial and aeolian sedimentation (Sherwood Sandstone Group), through marine-influenced playa lacustrine deposits (Mercia Mudstone Group) to marine environments (Penarth Group). A new tectono-stratigraphic model for the Sherwood Sandstone Group is proposed in which two major long-distance river systems developed under conditions of relative fault inactivity in the Early Triassic (Budleigh Salterton Pebble Beds and equivalent) and Middle Triassic (Otter Sandstone and equivalent). These are separated by a late Early Triassic syn-rift succession of fluvio–aeolian sandstones (Wildmoor Sandstone and Wilmslow Sandstone formations) and playa lacustrine muds (Nettlecombe Formation) which show major thickness variation and localisation with hanging wall basins. The partitioning of syn-rift deposits into mudstones within upstream basins (close to the source of water and sediment) and clean aeolian or fluvio–aeolian sandstones in downstream basins is similar to the pattern observed in the underlying late Permian. Under conditions of rapid tectonic subsidence chains of extensional basins may become disconnected with upstream basins (Wessex Basin) acting as traps for fines and water permitting more aeolian activity in temporarily unlinked downstream basins (Worcester and Cheshire basins). In addition to tectonic controls, fluctuating climate, relief related to limestone resilience in arid settings, the smoothing effect of fill and spill sedimentation and Tethyan sea-level change all contributed toward the observed Triassic stratigraphy in England.  相似文献   

Field Investigation of Vapor‐Phase‐Based Groundwater Monitoring     

David T. Adamson  Thomas E. McHugh  Michal W. Rysz  Roberto Landazuri  Charles J. Newell 《Ground Water Monitoring & Remediation》2012,32(1):59-72

The use of in‐field analysis of vapor‐phase samples to provide real‐time volatile organic compound (VOC) concentrations in groundwater has the potential to streamline monitoring by simplifying the sample collection and analysis process. A field validation program was completed to (1) evaluate methods for collection of vapor samples from monitoring wells and (2) evaluate the accuracy and precision of field‐portable instruments for the analysis of vapor‐phase samples. The field program evaluated three vapor‐phase sample collection methods: (1) headspace samples from two locations within the well, (2) passive vapor diffusion (PVD) samplers placed at the screened interval of the well, and (3) field vapor headspace analysis of groundwater samples. Two types of instruments were tested: a field‐portable gas chromatograph (GC) and a photoionization detector (PID). Field GC analysis of PVD samples showed no bias and good correlation to laboratory analysis of groundwater collected by low‐flow sampling (slope = 0.96, R² = 0.85) and laboratory analysis of passive water diffusion bag samples from the well screen (slope = 1.03; R² = 0.96). Field GC analysis of well headspace samples, either from the upper portion of the well or at the water‐vapor interface, resulted in higher variability and much poorer correlation (consistently biased low) relative to laboratory analysis of groundwater samples collected by low‐flow sample or passive diffusion bags (PDBs) (slope = 0.69 to 0.76; R² = 0.60 to 0.64). These results indicate that field analysis of vapor‐phase samples can be used to obtain accurate measurements of VOC concentrations in groundwater. However, vapor samples collected from the well headspace were not in equilibrium with water collected from the well screen. Instead, PVD samplers placed in the screened interval represent the most promising approach for field‐based measurement of groundwater concentrations using vapor monitoring techniques and will be the focus of further field testing.  相似文献   

Progress in Remediation of Groundwater at Petroleum Sites in California     

Thomas E. McHugh  Poonam R. Kulkarni  Charles J. Newell  John A. Connor  Sanjay Garg 《Ground water》2014,52(6):898-907

Quantifying the overall progress in remediation of contaminated groundwater has been a significant challenge. We utilized the GeoTracker database to evaluate the progress in groundwater remediation from 2001 to 2011 at over 12,000 sites in California with contaminated groundwater. This paper presents an analysis of analytical results from over 2.1 million groundwater samples representing at least $100 million in laboratory analytical costs. Overall, the evaluation of monitoring data shows a large decrease in groundwater concentrations of gasoline constituents. For benzene, half of the sites showed a decrease in concentration of 85% or more. For methyl tert‐butyl ether (MTBE), this decrease was 96% and for TBE, 87%. At remediation sites in California, the median source attenuation rate was 0.18/year for benzene and 0.36/year for MTBE, corresponding to half‐lives of 3.9 and 1.9 years, respectively. Attenuation rates were positive (i.e., decreasing concentration) for benzene at 76% of sites and for MTBE at 85% of sites. An evaluation of sites with active remediation technologies suggests differences in technology effectiveness. The median attenuation rates for benzene and MTBE are higher at sites with soil vapor extraction or air sparging compared with sites without these technologies. In contrast, there was little difference in attenuation rates at sites with or without soil excavation, dual phase extraction, or in situ enhanced biodegradation. The evaluation of remediation technologies, however, did not evaluate whether specific systems were well designed or implemented and did not control for potential differences in other site factors, such as soil type.  相似文献   

Time vs. Money: A Quantitative Evaluation of Monitoring Frequency vs. Monitoring Duration          下载免费PDF全文

Thomas E. McHugh  Poonam R. Kulkarni  Charles J. Newell 《Ground water》2016,54(5):692-698

The National Research Council has estimated that over 126,000 contaminated groundwater sites are unlikely to achieve low ug/L clean‐up goals in the foreseeable future. At these sites, cost‐effective, long‐term monitoring schemes are needed in order to understand the long‐term changes in contaminant concentrations. Current monitoring optimization schemes rely on site‐specific evaluations to optimize groundwater monitoring frequency. However, when using linear regression to estimate the long‐term zero‐order or first‐order contaminant attenuation rate, the effect of monitoring frequency and monitoring duration on the accuracy and confidence for the estimated attenuation rate is not site‐specific. For a fixed number of monitoring events, doubling the time between monitoring events (e.g., changing from quarterly monitoring to semi‐annual monitoring) will double the accuracy of estimated attenuation rate. For a fixed monitoring frequency (e.g., semi‐annual monitoring), increasing the number of monitoring events by 60% will double the accuracy of the estimated attenuation rate. Combining these two factors, doubling the time between monitoring events (e.g., quarterly monitoring to semi‐annual monitoring) while decreasing the total number of monitoring events by 38% will result in no change in the accuracy of the estimated attenuation rate. However, the time required to collect this dataset will increase by 25%. Understanding that the trade‐off between monitoring frequency and monitoring duration is not site‐specific should simplify the process of optimizing groundwater monitoring frequency at contaminated groundwater sites.  相似文献   

Characterization and Source History Modeling Using Low‐k Zone Profiles at Two Source Areas          下载免费PDF全文

David T. Adamson  Steven W. Chapman  Shahla K. Farhat  Beth L. Parker  Phillip deBlanc  Charles J. Newell 《Ground Water Monitoring & Remediation》2015,35(2):52-69

Like tree rings, high‐resolution soil sampling of low‐permeability (low‐k) zones can be used to evaluate the style of source history at contaminated sites (i.e., historical pattern of concentration and composition vs. time since releases occurred at the interface with the low‐k zone). This is valuable for the development of conceptual site model (CSM) and can serve as an important line of evidence supporting monitored natural attenuation (MNA) as a long‐term remedy. Source histories were successfully reconstructed at two sites at Naval Air Station Jacksonville using a simple one‐dimensional (1D) model. The plume arrival time and historical composition were reconstructed from the time initial releases that were suspected to occur decades earlier. At the first site (Building 106), the source reconstructions showed relatively constant source concentrations, but significant attenuation over time in the downgradient plume in the transmissive zone, suggesting MNA may not be an appropriate remedy if source control is a requirement, but attenuation processes are clearly helping to maintain plume stability and reduce risk. At the second site (Building 780), source concentrations in the transmissive zone showed an approximately a one order of magnitude over time, but apparently less attenuation in the downgradient plume. The source reconstruction method appeared to reflect site remediation efforts (excavation, soil vapor extraction) implemented in the 1990s. Finally, a detailed analysis using molecular biological tools, carbon isotopes, and by‐products suggests that most degradation activity is associated with high‐k zones but not with low‐k zones at these source areas. Overall, the source reconstruction methodology provided insight into historical concentration trends not obtainable otherwise given the limited long‐term monitoring data.  相似文献   

Urban resilience for whom,what, when,where, and why?     

Sara Meerow  Joshua P. Newell 《Urban geography》2019,40(3):309-329

ABSTRACT

In academic and policy discourse, the concept of urban resilience is proliferating. Social theorists, especially human geographers, have rightfully criticized that the underlying politics of resilience have been ignored and stress the importance of asking “resilience of what, to what, and for whom?” This paper calls for careful consideration of not just resilience for whom and what, but also where, when, and why. A three-phase process is introduced to enable these “five Ws” to be negotiated collectively and to engender critical reflection on the politics of urban resilience as plans, initiatives, and projects are conceived, discussed, and implemented. Deployed through the hypothetical case of green infrastructure in Los Angeles, the paper concludes by illustrating how resilience planning trade-offs and decisions affect outcomes over space and time, often with significant implications for equity.  相似文献